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Lithium-ion batteries dangerous?


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Recent speculation about lithium-ion batteries in the cargo hold of Malaysia Airlines 370 being a possible cause of the recent crash has got me thinking. Has anyone ever had a lithium-ion camera or laptop battery overheat and catch fire? Might airlines start banning them altogether, even in airplane cabins? If so, it would be very problematic for travelling photographers.

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Recent speculation about lithium-ion batteries in the cargo hold of Malaysia Airlines 370 being a possible cause of the recent crash has got me thinking. Has anyone ever had a lithium-ion camera or laptop battery overheat and catch fire? Might airlines start banning them altogether, even in airplane cabins? If so, it would be very problematic for travelling photographers.

 

Also anyone with a mobile phone as they also use the same type of batteries. Camera ones, as a rule, are a little more robust. They have a hard plastic shell whereas mobile phones often have a thickish metal foil wrapper that can be easily pierced. Once pierced, they can burst into flames.

 

In the UK now, you can only send parcels (by air) with these batteries if they are inside the actual equipment and not lose in a box (unless you are a wholesaler and they have special docs to complete I think). This would suggest their concerns are with the batteries being pierced and catching fire, the equipment would provide additional protection.

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When I go to the Post Office to send ANYTHING...even an medium size enveleope,the clerk will ask,'Anything liquid,fragile or perishable? Any batteries?'Once I've said no to all,then I have to sign the electronic device as 'No.'

 

I've always had a concern with those batteries. I put a small one in backwards into one of my cheapo ebay faux Pocket Wizards and within seconds it started smoking.

 

So I now ship cameras by UPS ground.

 

Does anyone know if draining the battery prior to shipping should be done?

 

Years ago someone suggested that.

 

Last time when I went out of town I ordered extra batteries and just had them sent to my destination.

 

 

L

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Lithium batteries are known to be vulnerable to overheating and are relatively inflammable. There was a major recall some 10 years ago of batteries in Dell, Sony, Apple, Toshiba, Hitachi etc products. That said, many billions are produced annually and are transported and used without  problem. I think that you have more chance of winning the lottery than having an issue with your battery. Our thoughts are with the poor souls, and their families, on the ill fated Malaysian flight.

 

dov

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Sony, HP and some other laptop brands once issued a waning a few years ago for some ion battery's since they could catch fire. All Battery's can blow up, I knew a friend who left a li-po battery on a dashboard of car one day. on a very hot day blew the car up.

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Lithium batteries can be dangerous if not treated with respect. i.e. overcharging, shorting terminals etc.

 

When one of the above occurs there is a chemical reaction which is self sustaining even when the power to the battery is cut off.

 

The reaction builds up heat and at temperatures above 160 degrees C the Lithium breaks down and releases gaseous oxygen, which increases pressure within the battery causing the case, either soft or hard, to burst and fire ensues. Because the Lithium is producing gaseous oxygen it immediately bursts into flame. It is not the oxygen in the surrounding atmosphere the causes the initial conflagration. There are also toxic by-products to be aware of so try not to breath the resulting smoke and fumes if you should be unfortunate enough to encounter a burning Lith battery.

 

Allan

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Lithium batteries can be dangerous if not treated with respect. i.e. overcharging, shorting terminals etc.

 

When one of the above occurs there is a chemical reaction which is self sustaining even when the power to the battery is cut off.

 

The reaction builds up heat and at temperatures above 160 degrees C the Lithium breaks down and releases gaseous oxygen, which increases pressure within the battery causing the case, either soft or hard, to burst and fire ensues. Because the Lithium is producing gaseous oxygen it immediately bursts into flame. It is not the oxygen in the surrounding atmosphere the causes the initial conflagration. There are also toxic by-products to be aware of so try not to breath the resulting smoke and fumes if you should be unfortunate enough to encounter a burning Lith battery.

 

Allan

 

Speaking of possible chemical reactions:

 

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Energy density.

If you want a battery to last for hundreds of exposures, live with the risk.

Otherwise we're back to strap-ons, ooer missus.

After recent problems with lithium-ion batteries in aircraft cargo holds, I have a feeling that there will be a rush to develop a less volatile alternative that will last for 100's of exposures. Personally, I wouldn't want to fly on a commercial jet with hundreds of pounds of lithium-ion batteries in the cargo bin like Malaysia 370.

 

Can't comment on your last line. Is it Shakespearean?

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Otherwise we're back to strap-ons, ooer missus.

Can't comment on your last line. Is it Shakespearean?

 

Brits have their own slang. :)

http://www.reddit.com/r/answers/comments/fftx6/can_a_uk_bloke_explain_ooh_err_missus_to_me/

 

As a native speaker of English you obviously expect to understand everything. Being Danish I know that I don't. The Internet is my friend.

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In the early days of Li-ion batteries my father had the battery in a Nikon Coolpix, and its replacement, overheat enough to distort the camera body; that was while the battery was in the camera. Would have been about contemporary with a spate of similar battery issues in other settings: laptops etc

 

I am sure there will already be effort going into alternative high power density electricity storage; cars, hand tools etc all currently relyon batteries that use nasty materials. But I suspect that high power density and highly reactive materials go  hand in hand, I am not an electro-chemist but will have a word with a chemical engineer friend who has worked with battery manufacturer when I next see him.

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Otherwise we're back to strap-ons, ooer missus.

Can't comment on your last line. Is it Shakespearean?

 

Brits have their own slang. :)

http://www.reddit.com/r/answers/comments/fftx6/can_a_uk_bloke_explain_ooh_err_missus_to_me/

 

As a native speaker of English you obviously expect to understand everything. Being Danish I know that I don't. The Internet is my friend.

 

My parents were both British, and I lived in London for a while as a kid. Nevertheless, I sometimes need the services of a translator. Thanks.

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Energy density.

If you want a battery to last for hundreds of exposures, live with the risk.

Otherwise we're back to strap-ons, ooer missus.

After recent problems with lithium-ion batteries in aircraft cargo holds, I have a feeling that there will be a rush to develop a less volatile alternative that will last for 100's of exposures. Personally, I wouldn't want to fly on a commercial jet with hundreds of pounds of lithium-ion batteries in the cargo bin like Malaysia 370.

 

Can't comment on your last line. Is it Shakespearean?

 

 

I wouldn't like to fly with that cargo either but I don't recall ever being told what would be in the hold when booking my flights :)

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Energy density.

If you want a battery to last for hundreds of exposures, live with the risk.

Otherwise we're back to strap-ons, ooer missus.

After recent problems with lithium-ion batteries in aircraft cargo holds, I have a feeling that there will be a rush to develop a less volatile alternative that will last for 100's of exposures. Personally, I wouldn't want to fly on a commercial jet with hundreds of pounds of lithium-ion batteries in the cargo bin like Malaysia 370.

 

Can't comment on your last line. Is it Shakespearean?

 

 

I wouldn't like to fly with that cargo either but I don't recall ever being told what would be in the hold when booking my flights :)

 

Yes, airline passengers certainly don't have many rights these days. Not only are we crammed into our seats like factory-farm chickens, but we also aren't told what dangers might be lurking beneath our feet. Who knows what the heck they've got stowed away down there in the cargo bin. 

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Does anyone know if draining the battery prior to shipping should be done?

 

 

Definately not. Li-ion and Li-polymer batteries should never be allowed to drop below 3v per cell. If they do, they are at risk of swelling and bursting into flames when next charged.

They should ideally be stored (and presumably posted) at half charge. I know this because I give li-po batteries some serious work to do racing electric model cars.

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I'm old enough to remember lead-acid batteries in my Mecablitz and Braun flashguns. They had to be charged and the acid topped up with distilled water from time to time. I still have the little squeezy bottle with a long thin nozzle that came with the Braun packs for that purpose. It sits in my toolbox now filled with oil for lubricating those important little places. 

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I'm old enough to remember lead-acid batteries in my Mecablitz and Braun flashguns. They had to be charged and the acid topped up with distilled water from time to time. I still have the little squeezy bottle with a long thin nozzle that came with the Braun packs for that purpose. It sits in my toolbox now filled with oil for lubricating those important little places. 

 

I'm old enough to remember the days we ran on coal gas. ;)

 

Allan

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